Amino acid

L-Valine

Also known as: L-valine, Val, BCAA, 2-amino-3-methylbutanoic acid

Overview

L-Valine is an essential branched-chain amino acid (BCAA) that plays a critical role in protein synthesis, energy production, and metabolic regulation. It is one of the three BCAAs—along with leucine and isoleucine—that are preferentially metabolized in skeletal muscle and contribute to muscle maintenance and recovery. BCAA supplementation, including valine, has been studied in clinical populations such as those with liver disease, where it may help correct the imbalanced ratio of BCAAs to aromatic amino acids (Fischer's ratio), potentially improving nutritional status and hepatic encephalopathy [1][6]. In patients with phenylketonuria (PKU), supplementation with large neutral amino acids like valine may competitively inhibit phenylalanine transport across the blood-brain barrier, reducing neurotoxic effects [3]. However, in certain inborn errors of metabolism such as methylmalonic acidemia (MMA), valine intake must be carefully restricted due to its catabolic pathway producing propionyl-CoA, which exacerbates metabolic instability [4]. No toxic effects of BCAA supplementation have been reported in clinical trials, suggesting a favorable safety profile in appropriate populations [1][6].

Dosage Guide

Recommended Daily Allowance

For generally healthy individuals

Adults (≥19 years)26 mg/kg/day(Estimated minimum requirement for essential amino acids; valine constitutes ~20% of total BCAAs)
Children (1-18 years)28-44 mg/kg/day(Higher per-kg needs during growth; valine requirement proportionally higher)

Therapeutic Doses

For treatment of specific conditions

Liver disease (e.g., cirrhosis)1-4 g/day as part of BCAA mixtureUsed to improve Fischer's ratio and nutritional status [1]
Phenylketonuria (PKU)500-1000 mg/day L-valine as part of LNAA supplementCompetes with phenylalanine for brain uptake [5][3]
Oncological peri-operative support3-6 g/day as part of BCAA formulationMay reduce muscle loss and improve recovery [7]

Upper Intake Limit

Maximum safe daily intake

mgNo established tolerable upper intake level for valine; high-dose BCAA supplements generally well-tolerated but long-term safety data limited. Imbalanced intake (e.g., excess leucine) may disrupt amino acid metabolism.

Special Forms

Alternative forms for specific needs

BCAA supplements (1:1:1 or 2:1:1 ratio with leucine:isoleucine:valine)

Exercise recovery, liver disease, sarcopenia

Medical foods with restricted valine

Inborn errors of metabolism (e.g., methylmalonic acidemia)

Clinical Notes

  • Avoid high-dose valine in patients with maple syrup urine disease (MSUD) or methylmalonic acidemia due to impaired catabolism.
  • In PKU, valine should be part of a balanced LNAA regimen; monitor plasma amino acid profiles.
  • Long-term high-dose BCAA supplementation should maintain balanced ratios to prevent amino acid imbalances.
  • No evidence of toxicity in clinical trials, but excessive isolated valine intake may disrupt transport of other large neutral amino acids across the blood-brain barrier.
  • Monitor liver and renal function in patients on long-term BCAA supplementation, especially in chronic disease states.

Research

Key FindingsPubMed
1

No toxic effects of BCAA supplementation reported in liver disease patients; potential benefit in correcting Fischer's ratio.

Role of branched-chain amino acids in liver disease: the evidence for and against.
Current opinion in clinical nutrition and metabolic care2007
2

1,500 mg oral valine was used in a crossover study to assess plasma kinetics; well-tolerated in healthy adults.

Dose-Response Absorption Kinetics of Oral L-Beta-Aminoisobutyric Acid (L-BAIBA) Supplementation in Healthy Men and Women.
Journal of dietary supplements2023
3

Large neutral amino acids like valine may reduce brain phenylalanine in PKU by competitive transport inhibition.

A proposal for an upper limit of leucine safe intake in healthy adults.
The Journal of nutrition2012
4

Valine is restricted in medical foods for methylmalonic acidemia due to metabolic risks from its catabolism.

A critical reappraisal of dietary practices in methylmalonic acidemia raises concerns about the safety of medical foods. Part 1: isolated methylmalonic acidemias.
Genetics in medicine : official journal of the American College of Medical Genetics2016
5

LNAA supplementation in PKU may improve brain amino acid profiles and cognitive outcomes.

Large neutral amino acids in the treatment of PKU: from theory to practice.
Journal of inherited metabolic disease2010
6

Oral L-BAIBA and valine (1,500 mg) were administered in healthy adults with no reported adverse events.

Dose-Response Absorption Kinetics of Oral L-Beta-Aminoisobutyric Acid (L-BAIBA) Supplementation in Healthy Men and Women.
Journal of dietary supplements2023
7

BCAA supplementation, including valine, was evaluated in cancer surgery patients; showed potential for improving nutritional status without significant safety concerns.

Are Supplemental Branched-Chain Amino Acids Beneficial During the Oncological Peri-Operative Period: A Systematic Review and Meta-Analysis.
Integrative cancer therapies2021
8

Ketoacid analogs of essential amino acids, including valine, may reduce nitrogen load in CKD, though specific dosing not established.

Is there a role for ketoacid supplements in the management of CKD?
American journal of kidney diseases : the official journal of the National Kidney Foundation2015

Products Containing L-Valine(1 report)