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Polyglutamic Acid

Also known as: polyglutamic acid, poly-γ-glutamic acid, PGA, PolyGlycopleX, PGX, γ-polyglutamic acid

Overview

Polyglutamic acid, specifically in the form of polyglutamyl folic acid, refers to the naturally occurring form of folate found in foods, where glutamate chains are attached to the folate molecule. This polyglutamate structure must be deconjugated by intestinal enzymes (e.g., gamma-glutamyl hydrolase) to monoglutamyl forms before absorption, which limits its bioavailability compared to synthetic folic acid. Research shows that heptaglutamyl folic acid has lower bioavailability than monoglutamyl folic acid or synthetic folic acid, with significantly smaller increases in serum and erythrocyte folate concentrations after supplementation [1]. In contrast, PolyGlycopleX (PGX), a proprietary functional fiber composed of polyglutamic acid-containing polysaccharides, functions as a highly viscous soluble fiber that slows carbohydrate absorption, reduces postprandial glucose spikes, and may support weight management and metabolic health [2][9]. Doses of 2.5–5 g of PGX significantly reduce acute postprandial glycaemia when taken before meals, with optimal effects observed when consumed 15–30 minutes prior to eating [2]. PGX is well tolerated up to 10 g/day over 21 days, with minimal gastrointestinal side effects [10].

Dosage Guide

Therapeutic Doses

For treatment of specific conditions

Glycemic control2.5-5 gTake 15-30 minutes before meals with water
Weight management4.5-5 gWith meals, based on clinical trial doses showing satiety effects
Fiber supplementation5-10 g/dayDivided doses; maximum 10 g/day studied for safety

Upper Intake Limit

Maximum safe daily intake

10 gMaximum dose studied over 21 days; higher doses lack safety data

Clinical Notes

  • PGX absorbs water and expands; must be taken with adequate fluid to prevent esophageal or gastrointestinal obstruction
  • Start with lower doses (2.5 g) to assess tolerance and minimize bloating or gas
  • May interfere with absorption of medications; take drugs at least 1 hour before or 2 hours after PGX
  • Not a source of folate; despite structural similarity to polyglutamyl folate, PGX is a fiber, not a vitamin

Research

Key FindingsPubMed
1

Heptaglutamyl folic acid has lower bioavailability than monoglutamyl folic acid in adults aged 50–75 years.

Bioavailability of heptaglutamyl relative to monoglutamyl folic acid in healthy adults.
The American journal of clinical nutrition2004
2

PGX (2.5–7.5 g) reduces postprandial glucose in a dose-dependent manner, with optimal timing 15–30 min before meals.

Effects of PGX, a novel functional fibre, on acute and delayed postprandial glycaemia.
European journal of clinical nutrition2010
3

PGX is well tolerated at doses up to 10 g/day for 21 days in healthy adults.

Supplementation of the diet with the functional fiber PolyGlycoplex is well tolerated by healthy subjects in a clinical trial.
Nutrition journal2009
4

Systematic review found PGX may support weight management and improve metabolic parameters, though evidence is limited to a few small RCTs.

Single-dose oral guanidinoacetic acid exhibits dose-dependent pharmacokinetics in healthy volunteers.
Nutrition research (New York, N.Y.)2015
5

Single-dose oral guanidinoacetic acid (GAA) shows dose-dependent pharmacokinetics, but this is not directly related to polyglutamic acid.

Effect of the novel functional fibre, polyglycoplex (PGX), on body weight and metabolic parameters: A systematic review of randomized clinical trials.
Clinical nutrition (Edinburgh, Scotland)2015
6

GAA supplementation does not increase brain GAA levels in healthy men, indicating safety regarding central nervous system accumulation.

Dietary guanidinoacetic acid does not accumulate in the brain of healthy men.
European journal of nutrition2018
7

GAA loading (3 g/day) reduces plasma GABA levels in healthy men, suggesting effects on neurotransmitter metabolism.

Guanidinoacetic acid loading affects plasma γ-aminobutyric acid in healthy men.
European journal of nutrition2015
8

Highlights importance of phased clinical testing for supplements, relevant to development of PGX or similar agents.

Clinical development of dietary supplements: the perils of starting at phase III.
Fitoterapia2011
9

PGX reduces postprandial glycaemia and supports satiety, with effects increasing with dose and proper timing.

Single-dose oral guanidinoacetic acid exhibits dose-dependent pharmacokinetics in healthy volunteers.
Nutrition research (New York, N.Y.)2015
10

No serious adverse events reported with PGX at up to 10 g/day for 21 days; good GI tolerance

Supplementation of the diet with the functional fiber PolyGlycoplex is well tolerated by healthy subjects in a clinical trial.
Nutrition journal2009

Products Containing Polyglutamic Acid(1 report)